[rayees-ac]

You can add flex-direction:column to flex-container

.flex-container {
  flex-direction: column;
}

Add display:inline-block to flex-item

.flex-item {
 display: inline-block;
}

because you added width and height has no effect on this element since it has a display of inline. Try adding display:inline-block or display:block. Learn more about width and height.

Also add to row class( you are given row{} not taken as style)

.row{
  width:100%;
  margin:0 auto;
  text-align:center;
}

Working Demo in Row :

.flex-container {
  padding: 0;
  margin: 0;
  list-style: none;
  display: flex;
  align-items: center;
  justify-content:center;
  flex-direction:column;
}
.row{
  width:100%;
  margin:0 auto;
  text-align:center;
}
.flex-item {
  background: tomato;
  padding: 5px;
  width: 200px;
  height: 150px;
  margin: 10px;
  line-height: 150px;
  color: white;
  font-weight: bold;
  font-size: 3em;
  text-align: center;
  display: inline-block;
}

<div class="flex-container">
  <div class="row">
    <span class="flex-item">1</span>
  </div>
  <div class="row">
    <span class="flex-item">2</span>
  </div>
  <div class="row">
    <span class="flex-item">3</span>
  </div>
  <div class="row">
    <span class="flex-item">4</span>
  </div>
</div>

Working Demo in Column :

.flex-container {
  padding: 0;
  margin: 0;
  width: 100%;
  list-style: none;
  display: flex;
  align-items: center;
}
.row {
  width: 100%;
}
.flex-item {
  background: tomato;
  padding: 5px;
  width: 200px;
  height: 150px;
  margin: 10px;
  line-height: 150px;
  color: white;
  font-weight: bold;
  font-size: 3em;
  text-align: center;
  display: inline-block;
}

<div class="flex-container">
  <div class="row">
    <span class="flex-item">1</span>
  </div>
  <div class="row">
    <span class="flex-item">2</span>
  </div>
  <div class="row">
    <span class="flex-item">3</span>
  </div>
  <div class="row">
    <span class="flex-item">4</span>
  </div>
</div>

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